Electron-Transfer-Induced Intramolecular Heck Carbonylation Reactions Leading to Benzolactones and Benzolactams

doi:10.1055/s-0037-1609964

Full metadata record

DC Field	Value	Language
dc.contributor.author	Fukuyama, Takahide	en_US
dc.contributor.author	Bando, Takanobu	en_US
dc.contributor.author	Ryu, Ilhyong	en_US
dc.date.accessioned	2018-08-21T05:53:52Z	-
dc.date.available	2018-08-21T05:53:52Z	-
dc.date.issued	2018-08-01	en_US
dc.identifier.issn	0039-7881	en_US
dc.identifier.uri	http://dx.doi.org/10.1055/s-0037-1609964	en_US
dc.identifier.uri	http://hdl.handle.net/11536/145276	-
dc.description.abstract	A metal-catalyst-free intramolecular Heck carbonylation reaction of benzyl alcohols and benzyl amines with carbon monoxide under heating at 250 degrees C affords the corresponding benzolactones and benzolactams in good to excellent yields. A hybrid radical/ionic chain mechanism, involving electron transfer from radical anions generated by nucleophilic attack of alcohols or amines on intermediate acyl radicals, is proposed.	en_US
dc.language.iso	en_US	en_US
dc.subject	carbonylation	en_US
dc.subject	electron transfer	en_US
dc.subject	radical reactions	en_US
dc.subject	metal-free	en_US
dc.subject	lactones	en_US
dc.subject	lactams	en_US
dc.title	Electron-Transfer-Induced Intramolecular Heck Carbonylation Reactions Leading to Benzolactones and Benzolactams	en_US
dc.type	Article	en_US
dc.identifier.doi	10.1055/s-0037-1609964	en_US
dc.identifier.journal	SYNTHESIS-STUTTGART	en_US
dc.citation.volume	50	en_US
dc.citation.spage	3015	en_US
dc.citation.epage	3021	en_US
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	Department of Applied Chemistry	en_US
dc.identifier.wosnumber	WOS:000439116100022	en_US
Appears in Collections:	Articles