Title: | Photoredox-Catalyzed Hydrodifluoroalkylation of Alkenes Using Difluorohaloalkyl Compounds and a Hantzsch Ester |
Authors: | Sumino, Shuhei Uno, Misae Fukuyarna, Takahide Ryu, Ilhyong Matsuura, Makoto Yasnarnoto, Akinori Kishikawa, Yosuke 應用化學系 Department of Applied Chemistry |
Issue Date: | 19-May-2017 |
Abstract: | Photoredox-catalyzed hydrodifluoroalkylation of alkenes proceeded smoothly in the presence of a Hantzsch ester as a hydrogen source under visible light irradiation. The reaction was also applicable to the hydrodifluoroalkylation of alkynes, and a continuous photo flow reaction was also successful. |
URI: | http://dx.doi.org/10.1021/acs.joc.7b00609 http://hdl.handle.net/11536/145547 |
ISSN: | 0022-3263 |
DOI: | 10.1021/acs.joc.7b00609 |
Journal: | JOURNAL OF ORGANIC CHEMISTRY |
Volume: | 82 |
Begin Page: | 5469 |
End Page: | 5474 |
Appears in Collections: | Articles |