Base-Catalyzed Povarov Reaction: An Unusual [1,3] Sigmatropic Rearrangement to Dihydropyrimidobenzimidazoles

Full metadata record

DC Field	Value	Language
dc.contributor.author	Chen, Chih-Hau	en_US
dc.contributor.author	Yellol, Gorakh S.	en_US
dc.contributor.author	Lin, Po-Tsung	en_US
dc.contributor.author	Sun, Chung-Ming	en_US
dc.date.accessioned	2014-12-08T15:20:43Z	-
dc.date.available	2014-12-08T15:20:43Z	-
dc.date.issued	2011-10-07	en_US
dc.identifier.issn	1523-7060	en_US
dc.identifier.uri	http://dx.doi.org/10.1021/ol201985p	en_US
dc.identifier.uri	http://hdl.handle.net/11536/14744	-
dc.description.abstract	A novel base-catalyzed Povarov reaction of arylamines, aldehydes, and electron-deficient dienophiles has been developed. An unprecedented in situ [1,3] sigmatropic rearrangement leading to 4,10-dihydropyrimido[1,2-a]benzimidazoles has also been discovered. An insight of the plausible mechanism is discussed and supported by X-ray crystal study. This cascade reaction is achieved in a one-pot multicomponent fashion on soluble support under microwave conditions.	en_US
dc.language.iso	en_US	en_US
dc.title	Base-Catalyzed Povarov Reaction: An Unusual [1,3] Sigmatropic Rearrangement to Dihydropyrimidobenzimidazoles	en_US
dc.type	Article	en_US
dc.identifier.doi	10.1021/ol201985p	en_US
dc.identifier.journal	ORGANIC LETTERS	en_US
dc.citation.volume	13	en_US
dc.citation.issue	19	en_US
dc.citation.spage	5120	en_US
dc.citation.epage	5123	en_US
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	Department of Applied Chemistry	en_US
dc.identifier.wosnumber	WOS:000295313900037	-
dc.citation.woscount	13	-
Appears in Collections:	Articles

Files in This Item:

If it is a zip file, please download the file and unzip it, then open index.html in a browser to view the full text content.