Title: Preparation and epoxy curing of p-nonylphenol/dicyclopentadiene adducts
Authors: Tseng, FP
Chang, FC
Lin, SF
Lin, JJ
應用化學系
Department of Applied Chemistry
Keywords: phenol;dicyclopentadiene;Jeffamine;epoxy curing
Issue Date: 28-Nov-1999
Abstract: Phenol/dicyclopentadiene adducts were prepared from the BF3-catalyzed reaction of p-nonylphenol and dicyclopentadiene at molar ratios of 2 : 1 and 3 : 2. These dicyclopentadiene-derived novolac products contain tricyclodecane and multiple phenol functionalities. In curing with diglycidyl ether of bisphenol A, the polymer properties were compared with those cured with formaldehyde novolac or Jeffamine D-400 amine. When p-nonylphenol/dicyclopentadiene adducts were mixed with other commercially available curing agents such as Jeffamine D-400 amine, the tricyclodecane functionality was introduced into the resulting epoxy network. The flexibility of the cured resin was improved due to the presence of the tricyclodecane moiety in the polymer structure. (C) 1999 John Wiley & Sons, Inc.
URI: http://hdl.handle.net/11536/30957
http://dx.doi.org/10.1002/(SICI)1097-4628(19991128)74:9<2196
ISSN: 0021-8995
DOI: 10.1002/(SICI)1097-4628(19991128)74:9<2196
Journal: JOURNAL OF APPLIED POLYMER SCIENCE
Volume: 74
Issue: 9
Begin Page: 2196
End Page: 2206
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